hey guys, i have some experience from the R/C hobby, let me share my experience with u.
NiMH, NiCD - these are your popular rechargable AAs. They can be discharged to full dicharge (0V), no problem. They also suffer from the "memory effect" whereby if you dont discharge it fully, after some cycles of use it will "remember" its "actual" lifespan, which means that if you dont discharge it fully, your batt life will drop significantly after awhile. but fret not, you can counter this by fuly charging and discharging your batt for a few cycles. in the RC world, there are dedicated DISchargers and chargers, and this is called "cycling" your batt. But take note, it wont recover your batt life 100%.
Li-ion/ Li-Po - these are the newer technologies... lighter, more energy density, etc etc. Also, no memory loss, so you can always charge it when it is half full. The critical thing about it is that Li-Pos CANNOT drop below a certain cutoff voltage, otherwise permanent harm will be done to your batt. In almost all devices, this is prevented by the machine showing "low batt" once the batt drops to the cutoff voltage. So dont worry, for LiPo, even when out of batt on your cam, it's not near the point where you are doing damage to it.
Storage wise, you'll need to take note, because batteries, for some reason, self discharge. Hence if you store your LiPo near the cut-off voltage, it might discharge and the voltage may drop to a dangerous level. Hence, for LiPos, always store them with at least half charge inside. For NiMh, it's better to fully discharge to prevent damage, then cycle them when u wanna use them to "wake them up".
I hope i've managed to show u all some tips on maintaining the diff kinds of batts. =)