I took some time to do a simple test of the focusing accuracy of my Canon 5D Mark III as follows:
i) I took a regular shot using phase detection focusing (non-liveview).
ii) I then immediately switched to contrast detection (liveview) and bumped up magnification 10x.
iii) I depressed the shutter button half way. The focus did not change at all.
I was very happy with the results of the test. Focus was bang on and the photo looked sharp.
I then used DPP to boost sharpness from an in-camera default of "3" to the maximum "10". The following photos show results of the post processing. EXIF Data can be found following the photos.
FULL PHOTO - SHARPENED IN DPP TO "10":
100% CROP:
BEFORE POST PROCESSING AND AFTER PROCESSING:
EXIF Data:
Camera Model: Canon EOS 5D Mark III
Shooting Mode: Aperture-Priority AE
Tv( Shutter Speed ): 1/100
Av( Aperture Value ): 3.2
Metering Mode: Evaluative Metering
Exposure Compensation: 0
ISO Speed: 125
Auto ISO Speed: ON
Lens: EF100mm f/2.8 Macro USM
Focal Length: 100.0mm
Image Size: 5760x3840
Image Quality: RAW
White Balance Mode: Auto
AF Mode: One-Shot AF
AF area select mode: Spot AF
Picture Style: Standard
Sharpness: 3
Contrast: 0
Saturation: 0
Color tone: 0
Color Space: sRGB
Live View Shooting: OFF