Well IF the 85mm is at f2.8, and the same distance from the object is from the 24-70 at 70mm at f2.8, then the DOF would be similar (well you can take into account that the 85mm is a little longer, but it won't be major).
but when you compare the 85mm shooting wide open compared to the 24-70, well then you can't compare, the 85 wins hands down. CA occurs for both lenses wide open. I reckon the 85mm at f2.8 stopped down may be sharper than the 24-70 at f2.8.
how's the 85mm AF speed? I'm also a big fan of taking my lenses into rain, especially the 105mm. Does the 85mm have a rubber gasket? (i doubt so). One last thing, do you reckon i'd find the 85mm too tight on DX since i do find the 105mm tight for some occasions but tend to work my way around it and recompose. It's a mere 20mm difference though (on DX 30, but meh)