Older memory stick is restricted to size of 128MB.. so it came out 256MB S2 selectable A or B of 128MB modules built into one.. Sony later introduce MS Pro which break the 128MB barrier.. nowadays you should able to see 256MB MS pro, 512MB and 1Gig.. They cost a bomb when were released..
MS Duo was introduced in the challenge of size.. MS DUO is comparable or smaller (have not seen or used b4) than SD/MMC XD cards.. there is a need for duo as the camera size grew smaller so does the memory card..
This is based purely on my opinion.. didnt really find out whats really behind it.. hope it helps..